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If you don’t want to bother with the bootloader like the other comment mentioned you can also just use the boot menu from the motherboard instead. You gotta mash f11 (or whatever it is on your motherboard) on boot when you want to go into Windows, but if you only need it every once in a while it is good enough.
Not who you replied to but I haven’t had any issues with a 3000 series card and LTSC, but I only used it for a whooping 12 hours since I got the card (I do 99% of gaming directly on Linux) so take my answer with a grain of salt.
I might be missing something but can’t you just manually download the drivers from the Nvidia website on LTSB?